Daryl - The Walking Dead - Biggest bad ass on TV, and he was in The Boondock Saints which makes him even cooler.
Jesse - Breaking Bad - So far I like him the most out of all the characters in the show. Walter is pretty cool, but so far I am not really taking as much of a liking to him as Jesse. However, I am only on season 2 episode 2, so my opinion may change.
Hank - Breaking Bad - He reminds me a lot of my own uncle, so I can really relate to him.
Reed - Criminal Minds - I love his level of intelligence, and I love learning little facts from him when I watch the show. I also love his story arc about his fight with schizophrenia (or what could be schizophrenia).
Thad - Blue Mountain State - He really does make the show. He is hilarious and I can't get enough of this show because of him.
Alex Moran - Blue Mountain State - I think he is one of the coolest characters in TV history. I really do aspire to be like him some day (minus the not wanting to go anywhere in life).