Hard Drive [Help please]

Ok so I'm building a new computer for a friend and I bought him a

Western Digital 1TB SATAII 7200rpm HDD.
He already has a WD SiliconEdge Blue SSC-D0064SC-2100 2.5" 64GB SATA II MLC Internal Solid State Drive

I want to know if their is anyway that I can use the SSD hardrive for boot and the 1TB HD for everything else and will they conflict or what not. I don't realy know much about raid 0 and such I just usually plug 1 HD in and away I go.

 

Nope you can use it as a slave for extra data.