Yes, if the bank account is linked to the paypal address, i use my debit card on my paypal..takes about 7days to transfer the funds though..
Also, make sure you have the money in the bank when you are transfering funds, because say, you put £50 into your paypal..but you take it out of your bank via a cash machine, Paypal will try to take it out, and it will fail, and you'll be £50 in debt because of an overdraft shit..
It's bullshit, it happened with me in NATWEST and i got £100 in debt, so i had to put the £100 i took out originally back in, or they would get the solicitors on me..